Pollution, Climate Change & International Environmental Cooperation

This chapter moves from the local to the planetary. It starts with the pollution you can measure on a street or in a river — the gases behind two very different kinds of smog, the indicators (AQI, DO, BOD, COD) that turn dirty air and water into numbers, and the rules for noise, plastic and electronic waste. It then climbs to the two global atmospheric problems that are constantly confused — ozone depletion and climate change — and lays out the science of the second carefully. The second half is the diplomacy: the Rio conventions, the road from Kyoto to Paris, the Montreal Protocol and its Kigali Amendment, the treaties on wildlife trade, migratory species and hazardous chemicals, India's NAPCC and its missions, and finally carbon markets. Treaty questions reward exact years and exact scope, so every treaty here is pinned to both.

Air Pollution: Pollutants, Smog and Standards

A primary pollutant is emitted directly from a source — sulphur dioxide from a coal plant, carbon monoxide from an engine, soot from a chimney. A secondary pollutant is not emitted at all; it forms in the air when primary pollutants react, often with the help of sunlight. Ground-level ozone, peroxyacetyl nitrate (PAN) and the sulphuric and nitric acids of acid rain are all secondary. This distinction explains why controlling ozone means controlling the gases that make it, not ozone itself.

Two kinds of smog
FeatureClassical (London) smogPhotochemical (Los Angeles) smog
IngredientsSmoke, soot and sulphur dioxide from coal, mixed with fogNitrogen oxides and volatile organic compounds from vehicles, acted on by sunlight
ConditionsCool, humid, still air — typically winterWarm, dry, sunny — typically summer afternoons
Chemical natureReducingOxidising
Key productsSulphur compounds, particulate matterOzone, PAN, aldehydes — eye irritation, damage to crops and rubber
🎯 Why winter air is worst
Normally air cools with height, so warm polluted air near the ground rises and disperses. On calm winter nights the ground loses heat fast and the air touching it becomes colder than the air above — a temperature inversion. The warm layer acts as a lid; pollution cannot rise through it and accumulates near the surface. Add low wind speeds, and a basin such as the Indo-Gangetic plain becomes a trap.

India's National Ambient Air Quality Standards (2009) set limits for twelve pollutants: PM10, PM2.5, sulphur dioxide, nitrogen dioxide, ozone, carbon monoxide, ammonia, lead, benzene, benzo(a)pyrene, arsenic and nickel. The National Air Quality Index, launched in 2014, uses eight of them — PM10, PM2.5, NO₂, SO₂, CO, O₃, NH₃ and lead — and reports the worst sub-index as the day's AQI. Carbon dioxide is not among them: it is a greenhouse gas, not a local air-quality pollutant in this sense. Acid rain is defined as rain with a pH below about 5.6, the value of clean rain in equilibrium with atmospheric carbon dioxide.

  • Bharat Stage VI emission norms for vehicles came into force across the country on 1 April 2020, with India moving straight from BS-IV and skipping BS-V.
  • The National Clean Air Programme (2019) sets city-level action plans for cities that repeatedly fail the standards (non-attainment cities).
  • The Commission for Air Quality Management in the National Capital Region and Adjoining Areas was given statutory form by a 2021 Act, to coordinate action across the States that share one airshed.

Water Pollution and Its Indicators

Organic waste — sewage, food-processing effluent, animal dung — is not poisonous in itself. It harms water because bacteria decomposing it consume dissolved oxygen, and fish and other aquatic life suffocate. So the key measures of water quality are all about oxygen.

The oxygen indicators
IndicatorWhat it measuresHow to read it
Dissolved Oxygen (DO)Oxygen actually present in the waterHigher is cleaner; falls as organic pollution and temperature rise
Biochemical Oxygen Demand (BOD)Oxygen that microorganisms need to decompose the biodegradable organic matter, over a fixed incubation period (classically five days at 20 °C)Higher is dirtier
Chemical Oxygen Demand (COD)Oxygen needed to oxidise all oxidisable matter, biodegradable or not, using a strong chemical oxidant (potassium dichromate)Higher is dirtier; COD is normally greater than BOD for the same sample
Faecal coliformsBacteria from human and animal gutIndicate sewage contamination and the risk of water-borne disease

The Central Pollution Control Board uses these indicators to classify river stretches by "designated best use". For outdoor bathing, for instance, its primary criteria include dissolved oxygen of at least 5 mg/L and BOD of not more than 3 mg/L, along with limits on faecal coliforms and pH. A river stretch that fails these figures is listed as a polluted stretch.

Diseases traced to specific water pollutants
DiseasePollutantNote
Minamata diseaseMercury (as methylmercury in fish)Nerve damage; first identified at Minamata Bay, Japan, in the 1950s
Itai-itai diseaseCadmiumPainful softening of bones; also first described in Japan
Blue baby syndrome (methaemoglobinaemia)Nitrate in drinking waterReduces the blood's capacity to carry oxygen in infants; linked to fertiliser run-off
Blackfoot disease; arsenicosisArsenic in groundwaterSkin lesions, gangrene of the extremities and cancers
FluorosisFluoride in excessMottled teeth, stiff and deformed bones
⚠️ Exam trap
BOD and DO move in opposite directions: as organic pollution rises, BOD goes up and DO comes down. Do not read "high oxygen demand" as "lots of oxygen". And remember that thermal pollution — hot water discharged from power plants — lowers DO even with no organic waste at all, because warm water holds less dissolved gas.

Soil, Noise, Plastic and E-waste

Noise is regulated by the Noise Pollution (Regulation and Control) Rules, 2000, framed under the Environment (Protection) Act. Limits are set in decibels on the A-weighted scale, dB(A), separately for day (6 a.m. to 10 p.m.) and night. A silence zone covers an area of not less than 100 metres around hospitals, educational institutions and courts.

Ambient noise limits, dB(A)
AreaDayNight
Industrial7570
Commercial6555
Residential5545
Silence zone5040
  • E-waste — discarded electronics contain lead, mercury, cadmium and brominated flame retardants, and are often dismantled informally by hand. The E-Waste (Management) Rules, 2022 (replacing the 2016 rules; India's first e-waste rules date from 2011) rest on Extended Producer Responsibility (EPR): producers must ensure that a set share of what they sell is collected and recycled, through registered recyclers.
  • Plastic — under the Plastic Waste Management Rules, 2016 as amended, identified single-use plastic items were banned from 1 July 2022, and the minimum thickness of plastic carry bags was raised to 120 microns from 31 December 2022. EPR applies to plastic packaging too.
  • Bio-medical waste — the 2016 rules require segregation at source by colour: yellow (anatomical and soiled waste, for incineration), red (contaminated recyclable plastics such as tubing and gloves), white translucent (sharps), and blue (glassware and metallic implants).
  • Soil and land — soil is degraded by erosion, salinisation and waterlogging from over-irrigation, excess fertiliser and pesticide, and mining and industrial waste. Under the desertification convention India has committed to restore 26 million hectares of degraded land by 2030, a target announced when India hosted the convention's conference in 2019.
🧠 Memory trick
Noise limits step down by ten from industrial to residential in the day — 75, 65, 55 — and the silence zone sits at 50/40. Night is always lower than day. If a question offers a silence-zone daytime limit of 55 or 65, it has borrowed the residential or commercial figure.

Ozone Depletion and the Montreal Protocol

Most of the atmosphere's ozone lies in the stratosphere, roughly 15 to 35 km above the surface, where it absorbs most of the Sun's harmful UV-B radiation. Its total amount in a column of air is measured in Dobson Units (DU); an "ozone hole" is a region where the column falls below 220 DU. The hole appears over Antarctica in the southern spring (September–October): in the dark polar winter, polar stratospheric clouds form at extremely low temperatures, and on their surfaces chlorine from CFCs is converted into reactive forms; when sunlight returns, it destroys ozone rapidly. A single chlorine atom can destroy thousands of ozone molecules, and bromine (from halons and methyl bromide) is even more destructive per atom.

The ozone treaties
InstrumentAdopted · in forceWhat it does
Vienna Convention1985 · 1988Framework for cooperation and research on the ozone layer; no binding cuts
Montreal Protocol1987 · 1989Binding, scheduled phase-out of ozone-depleting substances — CFCs, halons, carbon tetrachloride, methyl chloroform, methyl bromide, and the transitional HCFCs. In 2009 it became the first treaty in UN history to be ratified by every country
Kigali Amendment2016 · 2019Adds a phase-down of HFCs — gases that do not harm ozone but are powerful greenhouse gases

The Kigali Amendment gives different schedules to different groups. Developed countries began their reduction in 2019 and cut by 85% by 2036. Most developing countries, including China, freeze in 2024 and cut 80% by 2045. India, with a few others, freezes in 2028 and reduces by 85% by 2047, from a 2024–26 baseline. India ratified the amendment in 2021, and in 2019 it released the India Cooling Action Plan, among the first national plans to treat cooling demand — and therefore refrigerant gases — as a single policy problem.

⚠️ Exam trap
Three gases, three verdicts. CFCs deplete ozone and warm the climate. HCFCs deplete ozone far less and were allowed as a stop-gap, now being phased out too. HFCs have zero ozone-depleting potential but a high global warming potential — which is why they were the answer to the ozone problem and then became a climate problem, controlled by Kigali. So Kigali is an ozone treaty amendment whose purpose is climate.

The Science of Climate Change

Carbon dioxide in the air stood at about 280 parts per million (ppm) before industrialisation and has risen to more than 420 ppm in recent years, mainly from burning fossil fuels and clearing forests. The IPCC's Sixth Assessment Report (2021–2023) concluded that it is "unequivocal" that human influence has warmed the atmosphere, ocean and land, and that global surface temperature in 2011–2020 was about 1.1 °C above the 1850–1900 average. The gases differ in how strongly and how long they trap heat, which is captured by the Global Warming Potential (GWP) — the warming caused by a gas over a set period (usually 100 years) relative to the same mass of CO₂.

The Kyoto "basket" of greenhouse gases (100-year GWP, IPCC Fifth Assessment)
GasMain human sourcesGWP (100 yr)
Carbon dioxide (CO₂)Fossil fuels, cement, deforestation1 (the reference)
Methane (CH₄)Paddy fields, livestock digestion, landfills, leaks from gas and coalAbout 28
Nitrous oxide (N₂O)Nitrogen fertilisers, some industrial processesAbout 265
Hydrofluorocarbons (HFCs)Refrigeration and air-conditioningRanges widely, up to thousands
Perfluorocarbons (PFCs)Aluminium smelting, electronicsThousands
Sulphur hexafluoride (SF₆)Insulation in high-voltage electrical equipmentAbout 23,500 — the highest in the basket
  • Nitrogen trifluoride (NF₃) was added to the list for the Kyoto Protocol's second commitment period. Water vapour is the most abundant greenhouse gas, but it acts as a feedback — warmer air holds more of it — rather than as a gas humans emit directly to drive the change.
  • Aerosols pull the other way: sulphate particles reflect sunlight and cool the planet, masking part of the warming. Black carbon (soot) is the exception — it absorbs sunlight and, settling on snow and ice, darkens them and speeds melting. It is a short-lived climate pollutant, not part of the Kyoto basket.
  • Positive feedbacks amplify warming: melting ice exposes darker sea and land that absorb more heat (ice–albedo feedback), and thawing permafrost can release stored carbon as CO₂ and methane.
  • Ocean acidification is the "other CO₂ problem": the oceans absorb roughly a quarter of the CO₂ we emit, forming carbonic acid, which lowers the pH of sea water and makes it harder for corals, molluscs and some plankton to build calcium carbonate shells and skeletons.
Words used in climate policy
TermMeaning
MitigationReducing emissions or enhancing sinks — tackling the cause
AdaptationAdjusting to impacts already happening or expected — drought-tolerant seeds, cyclone shelters, heat action plans
Net zeroRemaining emissions balanced by an equal amount removed from the atmosphere
Carbon sequestrationCapturing and storing carbon — in forests and soils, or geologically after industrial capture
GeoengineeringDeliberate large-scale intervention — e.g. reflecting sunlight with stratospheric aerosols, or ocean fertilisation with iron to stimulate plankton
⚠️ Exam trap
GWP and total contribution are different questions. SF₆ has the highest GWP of the basket, but CO₂ causes the most warming overall because so much more of it is emitted and it lasts for centuries. Methane is roughly 28 times as potent as CO₂ over 100 years but stays in the air only about a decade, which is why cutting methane is the fastest lever on near-term warming.

The Climate Regime: From Stockholm to Paris and Beyond

Milestones of global environmental diplomacy
  1. 1972
    Stockholm Conference on the Human Environment — the first global environmental summit; created UNEP (headquarters Nairobi); 5 June became World Environment Day
  2. 1987
    Brundtland Report, *Our Common Future* — defined sustainable development as meeting the needs of the present without compromising the ability of future generations to meet their own needs
  3. 1992
    Rio Earth Summit (UNCED) — opened the UNFCCC and the CBD for signature, and adopted the Rio Declaration, Agenda 21 and the Forest Principles; it also launched the negotiation of the desertification convention (UNCCD, adopted 1994)
  4. 1997
    Kyoto Protocol (COP-3) — binding targets for developed countries; in force 2005; first commitment period 2008–2012, extended to 2013–2020 by the Doha Amendment
  5. 2009–2010
    Copenhagen (COP-15) — developed countries pledged to mobilise $100 billion a year by 2020; Cancún (COP-16) established the Green Climate Fund
  6. 2013
    Warsaw (COP-19) — the Warsaw Framework for REDD+ and the Warsaw International Mechanism on loss and damage
  7. 2015
    Paris Agreement (COP-21) — universal, built on nationally determined contributions; in force 4 November 2016
  8. 2021
    Glasgow (COP-26) — the Glasgow Climate Pact called for a "phase-down" of unabated coal power (softened from "phase-out"); Article 6 rules on carbon markets largely agreed
  9. 2022–2023
    Sharm el-Sheikh (COP-27) agreed to create a loss and damage fund; Dubai (COP-28) made it operational, concluded the first global stocktake and called for transitioning away from fossil fuels in energy systems
  10. 2024
    Baku (COP-29) — a new collective finance goal of at least $300 billion a year by 2035 for developing countries; Article 6 rules completed
Kyoto and Paris compared
FeatureKyoto Protocol (1997)Paris Agreement (2015)
Who cutsOnly developed (Annex I) countries had binding targetsAll parties, through Nationally Determined Contributions (NDCs)
ApproachTop-down — targets negotiated and assignedBottom-up — each country sets its own, then raises ambition
Binding elementThe emission targets themselvesThe process — preparing, communicating and reporting on NDCs is mandatory; achieving them is not legally enforced
Review cycleFixed commitment periodsNew or updated NDCs every five years; a global stocktake every five years (first in 2023)
GoalCollective reduction for Annex I countries against 1990 levelsHold warming well below 2 °C and pursue 1.5 °C; balance sources and sinks in the second half of the century

Both treaties rest on the UNFCCC principle of common but differentiated responsibilities and respective capabilities (CBDR–RC): every country shares the duty to act, but those that emitted most historically and can afford most should do most. India ratified the Paris Agreement on 2 October 2016. Its first NDC (2015) pledged a 33–35% cut in the emission intensity of GDP by 2030 from 2005 levels and 40% of installed power capacity from non-fossil sources — the latter reached in 2021, years early. The updated NDC (2022) raised these to 45% and about 50%, and kept the pledge of an additional carbon sink of 2.5–3 billion tonnes of CO₂-equivalent through more forest and tree cover by 2030. At COP-26 India announced the "Panchamrit", including 500 GW of non-fossil capacity by 2030 and net-zero emissions by 2070, and it submitted its Long-Term Low-Emission Development Strategy at COP-27.

  • International Solar Alliance — launched by India and France at COP-21 in Paris (2015); headquarters at Gurugram, Haryana.
  • Coalition for Disaster Resilient Infrastructure (CDRI) — launched by India at the UN Climate Action Summit in New York (2019); secretariat in New Delhi.
  • Mission LiFE (Lifestyle for Environment) — launched in 2022 to promote individual and community behaviour that uses resources mindfully.
⚠️ Exam trap
India's targets are about emission intensity (emissions per unit of GDP), not absolute emissions — absolute emissions can rise while intensity falls. And the 50% non-fossil target is about installed electric power capacity, not about all energy or all electricity generated. Questions often swap these words.

Biodiversity, Wildlife-Trade and Chemicals Conventions

The Convention on Biological Diversity (CBD), opened at Rio in 1992 and in force from 1993, has three objectives: conservation of biodiversity, sustainable use of its components, and fair and equitable sharing of benefits from genetic resources. Two protocols sit under it: the Cartagena Protocol on Biosafety (adopted 2000, in force 2003), on the safe transfer of living modified organisms, and the Nagoya Protocol (adopted 2010, in force 2014), on access and benefit-sharing. The 2010 Aichi Biodiversity Targets (twenty, for 2011–2020) were followed in December 2022 by the Kunming–Montreal Global Biodiversity Framework, with 23 targets for 2030 — the best known being "30 by 30", to conserve 30% of the world's land and 30% of its oceans by 2030. India hosted CBD COP-11 at Hyderabad in 2012. The United States is not a party to the CBD.

Wildlife and land conventions
ConventionSigned · in forceScope and structure
CITES (Washington Convention)1973 · 1975 (India 1976)Regulates international trade in wild animals and plants. Appendix I — species threatened with extinction; commercial trade generally prohibited. Appendix II — not necessarily threatened now, but trade must be controlled. Appendix III — listed by one party that asks others to help control trade. Binding on parties, but works through their national laws. 3 March (its signing date) is World Wildlife Day
CMS (Bonn Convention on Migratory Species)1979 · 1983 (India 1983)Appendix I — endangered migratory species, to be strictly protected; Appendix II — species needing international cooperation. India hosted COP-13 at Gandhinagar (2020), where the Great Indian bustard, the Asian elephant and the Bengal florican were added to Appendix I
Ramsar Convention1971 · 1975 (India 1982)Wetlands of international importance; outside the UN system
UNCCD (desertification)1994 · 1996Combats desertification and land degradation in drylands; the third Rio convention. 17 June is the World Day to Combat Desertification and Drought. India hosted COP-14 (2019)
The chemicals and waste conventions
ConventionAdopted · in forceWhat it controls
Basel Convention1989 · 1992Transboundary movements of hazardous wastes and their disposal — aimed at stopping the dumping of rich countries' waste in poorer ones; plastic waste was brought under its controls by later amendments
Rotterdam Convention1998 · 2004Prior Informed Consent (PIC) procedure for certain hazardous chemicals and pesticides in international trade — an importing country must be told and must agree
Stockholm Convention2001 · 2004Persistent Organic Pollutants (POPs) — eliminating or restricting them, beginning with the "dirty dozen" that included DDT, aldrin and PCBs
Minamata Convention2013 · 2017 (India ratified 2018)Mercury — its mining, use in products and processes, emissions and waste; named after the Japanese mercury-poisoning disaster
🧠 Memory trick
Match the three chemical conventions by their verbs: Basel moves (waste across borders), Rotterdam informs (consent before trade), Stockholm eliminates (POPs). Basel, Rotterdam and Stockholm share a joint secretariat; Minamata stands alone, devoted to one element. For wildlife: CITES trades, CMS migrates, Ramsar wets.

India's National Action Plan on Climate Change

The National Action Plan on Climate Change (NAPCC) was released on 30 June 2008 by the Prime Minister's Council on Climate Change. It does not set emission caps; it organises India's response through eight National Missions, each led by a ministry, that are meant to deliver development and climate benefits together. States prepare their own State Action Plans on Climate Change, and a National Adaptation Fund for Climate Change (2015) finances adaptation projects in vulnerable sectors.

The eight National Missions
MissionLead ministry / departmentFocus
National Solar MissionNew and Renewable EnergyLaunched in 2010 with a target of 20 GW of solar by 2022, raised in 2015 to 100 GW
National Mission for Enhanced Energy EfficiencyPower (Bureau of Energy Efficiency)Includes Perform, Achieve and Trade (PAT) — energy-intensive plants get targets and trade Energy Saving Certificates
National Mission on Sustainable HabitatHousing and Urban AffairsEnergy-efficient buildings, urban planning, public transport, waste management
National Water MissionJal ShaktiRaise water-use efficiency by 20%; integrated water-resource management
National Mission for Sustaining the Himalayan EcosystemScience and TechnologyGlaciers, mountain ecosystems and communities
National Mission for a Green IndiaEnvironment, Forest and Climate ChangeIncrease forest and tree cover on 5 million hectares and improve its quality on another 5 million hectares
National Mission for Sustainable AgricultureAgriculture and Farmers WelfareClimate-resilient farming, soil health, dryland agriculture
National Mission on Strategic Knowledge for Climate ChangeScience and TechnologyResearch networks, climate modelling and data
🧠 Memory trick
Group the eight as two energy (Solar, Energy Efficiency), three resource (Water, Green India, Sustainable Agriculture), two place (Sustainable Habitat, Himalayan Ecosystem) and one knowledge (Strategic Knowledge). Nuclear power, coal and wind are not missions of the NAPCC — a frequent distractor.

Carbon Markets and Pricing

A carbon market puts a price on emissions so that cuts happen wherever they are cheapest. The unit is the carbon credit: one tonne of CO₂ or its equivalent in another greenhouse gas. In a cap-and-trade system a regulator fixes a total cap and issues allowances; a firm that cuts more than it must can sell its spare allowances to one that cuts less. In a baseline-and-credit system a project earns credits for reducing emissions below what would otherwise have happened. Compliance markets are created by law; voluntary markets serve companies and individuals offsetting by choice, and their quality depends heavily on whether the reductions are real, additional and permanent.

Carbon-market mechanisms under the climate treaties
MechanismTreatyHow it works
International Emissions TradingKyotoAnnex I countries trade parts of their assigned emission amounts
Clean Development Mechanism (CDM)KyotoProjects in developing countries earn Certified Emission Reductions (CERs) that developed countries can use toward their targets — India hosted a large number of CDM projects
Joint ImplementationKyotoProjects in one Annex I country earn credits for another
Article 6.2 — cooperative approachesParisCountries transfer Internationally Transferred Mitigation Outcomes (ITMOs) bilaterally, with corresponding adjustments so a cut is not counted twice
Article 6.4 — crediting mechanismParisA centralised, UN-supervised mechanism — the successor to the CDM

India is building a domestic market. The Energy Conservation (Amendment) Act, 2022 empowered the Central government to specify a carbon-credit trading scheme, and the Carbon Credit Trading Scheme, 2023 was notified under the Energy Conservation Act, 2001. It creates the Indian Carbon Market, with the Bureau of Energy Efficiency as administrator: obligated industries receive greenhouse-gas emission-intensity targets and can trade carbon credit certificates, alongside an offset mechanism for voluntary projects. It builds on older market instruments — the PAT scheme's Energy Saving Certificates and Renewable Energy Certificates. Separately, the Green Credit Programme (2023), notified under the Environment (Protection) Act, rewards actions such as tree planting and water conservation with green credits; it is an environmental incentive, not a carbon credit. India also taxed coal through a cess introduced in 2010, later subsumed into the GST compensation cess in 2017.

  • REDD+ — Reducing Emissions from Deforestation and forest Degradation, plus conservation, sustainable management of forests and enhancement of forest carbon stocks: results-based payments to developing countries for keeping forests standing.
  • Carbon Border Adjustment Mechanism (CBAM) — the European Union's charge on the embedded carbon of certain imports such as steel, aluminium and cement; reporting began in October 2023, with financial obligations from 2026. It matters to Indian exporters because it prices carbon at the border.
⚠️ Exam trap
Three Indian certificates, three different things. Energy Saving Certificates come from PAT and count energy saved; Renewable Energy Certificates represent green electricity generated; carbon credit certificates under the 2023 scheme count greenhouse-gas reductions. And the Green Credit Programme is not a carbon market at all — it rewards environmental actions under the Environment (Protection) Act, while the carbon market sits under the Energy Conservation Act.

Key takeaways

  • Secondary pollutants (ground-level ozone, PAN, acid-rain acids) form in the air. Classical smog = coal smoke + SO₂ + fog, winter, reducing; photochemical smog = NOx + VOCs + sunlight, summer, oxidising. NAAQS cover 12 pollutants; the AQI uses 8 (PM10, PM2.5, NO₂, SO₂, CO, O₃, NH₃, lead) — not CO₂. Acid rain: pH below about 5.6.
  • DO high = clean; BOD and COD high = dirty; COD ≥ BOD because a chemical oxidant attacks non-biodegradable matter too. Minamata — mercury; itai-itai — cadmium; blue baby — nitrate; blackfoot — arsenic; fluorosis — fluoride. Noise limits by day: industrial 75, commercial 65, residential 55, silence zone 50 dB(A).
  • Ozone hole: Antarctic spring, polar stratospheric clouds, chlorine from CFCs, below 220 DU. Vienna 1985 → Montreal 1987 (universal ratification in 2009) → Kigali 2016 (in force 2019, HFC phase-down); India freezes HFCs in 2028 and cuts 85% by 2047. HFCs have zero ozone-depleting potential but high GWP.
  • CO₂: ~280 ppm pre-industrial → over 420 ppm; IPCC AR6: human influence "unequivocal", ~1.1 °C warming. Kyoto basket: CO₂, CH₄, N₂O, HFCs, PFCs, SF₆ (+NF₃ later); SF₆ has the highest GWP, CO₂ the largest total effect. Aerosols cool; black carbon warms; ocean acidification threatens calcifying life.
  • Stockholm 1972 (UNEP) → Brundtland 1987 → Rio 1992 (UNFCCC, CBD; UNCCD 1994) → Kyoto 1997/2005 → Copenhagen 2009 ($100 bn) → Paris 2015/2016 → Glasgow 2021 (coal phase-down) → COP-27/28 (loss and damage fund, first global stocktake) → Baku 2024 ($300 bn by 2035). Kyoto: binding, Annex I only; Paris: universal NDCs every five years.
  • India: 45% cut in emission intensity of GDP and ~50% non-fossil installed power capacity by 2030 (2022 NDC), 2.5–3 Gt CO₂e extra sink, net zero by 2070; ISA (Gurugram), CDRI, Mission LiFE. NAPCC (2008) has eight missions — Solar, Energy Efficiency, Sustainable Habitat, Water, Himalayan Ecosystem, Green India, Sustainable Agriculture, Strategic Knowledge.
  • CBD (Cartagena 2000 biosafety, Nagoya 2010 ABS, Kunming–Montreal 2022 with "30 by 30"); CITES 1973 (Appendix I bans commercial trade); CMS 1979 (COP-13 Gandhinagar 2020); Basel wastes, Rotterdam PIC, Stockholm POPs, Minamata mercury. India's Carbon Credit Trading Scheme 2023 sits under the Energy Conservation Act; the Green Credit Programme is not a carbon market.

Practice questions (16)

Attempt each one before opening the answer. Every explanation names the tempting wrong option as well as the right one, because that is where marks are lost.

  1. Which of the following is a secondary pollutant characteristic of photochemical smog?

    1. Carbon monoxide
    2. Sulphur dioxide
    3. Peroxyacetyl nitrate (PAN)
    4. Fly ash
    Show answer

    Answer: C — Peroxyacetyl nitrate (PAN)

    PAN is not emitted by any source; it forms in the air when nitrogen oxides and volatile organic compounds react in sunlight, alongside ground-level ozone. Carbon monoxide, sulphur dioxide and fly ash are all primary pollutants released directly from engines, chimneys and power plants.
  2. Consider the following statements:
    1. Classical (London-type) smog typically forms in cool, humid conditions and is reducing in nature.
    2. Photochemical smog requires sunlight and is oxidising in nature.
    Which of the statements given above is/are correct?

    1. Only 1
    2. Only 2
    3. Both 1 and 2
    4. Neither 1 nor 2
    Show answer

    Answer: C — Both 1 and 2

    Both are correct. Classical smog is coal smoke and sulphur dioxide mixed with winter fog, and it is chemically reducing. Photochemical smog forms when sunlight drives reactions between nitrogen oxides and hydrocarbons, producing oxidants such as ozone and PAN.
  3. Which one of the following is NOT among the eight pollutants used to calculate India's National Air Quality Index?

    1. Ammonia (NH₃)
    2. Lead (Pb)
    3. Carbon dioxide (CO₂)
    4. Ground-level ozone (O₃)
    Show answer

    Answer: C — Carbon dioxide (CO₂)

    The AQI uses PM10, PM2.5, NO₂, SO₂, CO, O₃, NH₃ and lead. Carbon dioxide is a greenhouse gas rather than a local air-quality pollutant in this sense, so it is not part of the index — a common trap because carbon monoxide (CO) is.
  4. Consider the following statements about water-quality indicators:
    1. A high Biochemical Oxygen Demand (BOD) indicates heavily polluted water.
    2. The Chemical Oxygen Demand (COD) of a sample is normally higher than its BOD.
    3. Dissolved oxygen rises as organic pollution increases.
    Which of the statements given above are correct?

    1. 1 and 2 only
    2. 2 and 3 only
    3. 1 and 3 only
    4. 1, 2 and 3
    Show answer

    Answer: A — 1 and 2 only

    Statements 1 and 2 are correct: COD counts everything a strong chemical oxidant can attack, biodegradable or not, so it exceeds BOD. Statement 3 is reversed — microbes decomposing organic waste use up oxygen, so dissolved oxygen falls as pollution rises.
  5. Which one of the following pairs of disease and causative pollutant is NOT correctly matched?

    1. Minamata disease — mercury
    2. Itai-itai — cadmium
    3. Blue baby syndrome — nitrate
    4. Blackfoot disease — fluoride poisoning
    Show answer

    Answer: D — Blackfoot disease — fluoride poisoning

    Blackfoot disease, with gangrene of the feet, is caused by arsenic in groundwater; excess fluoride causes fluorosis of teeth and bones instead. The other three pairs are correct — mercury, cadmium and nitrate respectively.
  6. Under the Noise Pollution (Regulation and Control) Rules, 2000, the daytime ambient noise limit for a silence zone is:

    1. 40 dB(A)
    2. 50 dB(A)
    3. 55 dB(A)
    4. 75 dB(A)
    Show answer

    Answer: B — 50 dB(A)

    A silence zone is limited to 50 dB(A) by day and 40 dB(A) by night. 40 is the night-time figure, 55 is the residential daytime limit and 75 the industrial daytime limit — each a real number from the same table, which is what makes them tempting.
  7. Consider the following statements:
    1. The E-Waste (Management) Rules, 2022 are based on the principle of Extended Producer Responsibility.
    2. India banned identified single-use plastic items with effect from 1 July 2022.
    3. After 2022, plastic carry bags of any thickness may be sold freely.
    Which of the statements given above are correct?

    1. 1 and 2 only
    2. 2 and 3 only
    3. 1 and 3 only
    4. 1, 2 and 3
    Show answer

    Answer: A — 1 and 2 only

    Statements 1 and 2 are correct. Statement 3 is wrong: the minimum thickness of plastic carry bags was raised, to 120 microns from 31 December 2022, so thin bags remain prohibited. EPR obliges producers to ensure collection and recycling of what they sell.
  8. The Kigali Amendment (2016) to the Montreal Protocol provides for the phase-down of:

    1. chlorofluorocarbons
    2. hydrofluorocarbons
    3. halons
    4. methyl bromide
    Show answer

    Answer: B — hydrofluorocarbons

    Kigali brought hydrofluorocarbons (HFCs) under the Montreal Protocol. HFCs do not deplete ozone but are powerful greenhouse gases, so the amendment serves the climate. CFCs, halons and methyl bromide were already controlled by the original Protocol as ozone-depleting substances.
  9. Consider the following statements:
    1. Hydrofluorocarbons do not deplete the ozone layer but are potent greenhouse gases.
    2. Under the Kigali Amendment, India is to freeze its consumption of HFCs in 2028.
    3. The Montreal Protocol was the first treaty in United Nations history to achieve universal ratification.
    How many of the statements given above are correct?

    1. Only one
    2. Only two
    3. All three
    4. None
    Show answer

    Answer: C — All three

    All three are correct. HFCs have zero ozone-depleting potential but a high global warming potential; India's group freezes in 2028 and cuts 85% by 2047; and in 2009 the Montreal Protocol became the first UN treaty ratified by every country. The trap is to assume that 2024 — the freeze year for China and most developing countries — applies to India.
  10. Among the following greenhouse gases of the Kyoto basket, which has the highest 100-year global warming potential?

    1. Carbon dioxide
    2. Methane
    3. Nitrous oxide
    4. Sulphur hexafluoride
    Show answer

    Answer: D — Sulphur hexafluoride

    Sulphur hexafluoride has a GWP of about 23,500 over 100 years — the highest in the basket. Carbon dioxide is the reference gas with a GWP of 1, even though it causes the most warming overall because of the sheer quantity emitted; methane is about 28 and nitrous oxide about 265.
  11. Consider the following statements:
    1. The Kyoto Protocol set legally binding emission targets only for developed (Annex I) countries.
    2. Under the Paris Agreement, parties communicate new or updated NDCs every five years.
    3. The Paris Agreement entered into force in 2005.
    Which of the statements given above are correct?

    1. 1 and 2 only
    2. 2 and 3 only
    3. 1 and 3 only
    4. 1, 2 and 3
    Show answer

    Answer: A — 1 and 2 only

    Statements 1 and 2 are correct. Statement 3 confuses the two treaties: 2005 is when the Kyoto Protocol entered into force; the Paris Agreement entered into force on 4 November 2016, less than a year after its adoption.
  12. Which one of the following is NOT one of the three "Rio conventions"?

    1. UNFCCC
    2. CBD
    3. UNCCD
    4. CITES
    Show answer

    Answer: D — CITES

    The three Rio conventions are the UNFCCC and the CBD, opened at the 1992 Earth Summit, and the UNCCD, whose negotiation the summit launched and which was adopted in 1994. CITES is much older — signed at Washington in 1973 — and regulates trade in wildlife.
  13. Under CITES, species threatened with extinction, in which commercial international trade is generally prohibited, are listed in:

    1. Appendix I
    2. Appendix II
    3. Appendix III
    4. Schedule I
    Show answer

    Answer: A — Appendix I

    Appendix I covers species threatened with extinction. Appendix II covers species whose trade must be controlled to avoid that fate, and Appendix III species listed by a single party seeking help. "Schedule I" is a schedule of India's Wild Life (Protection) Act, not a CITES list.
  14. Consider the following pairs (convention : subject):
    1. Basel Convention : transboundary movements of hazardous wastes
    2. Rotterdam Convention : persistent organic pollutants
    3. Minamata Convention : mercury
    How many of the pairs given above are correctly matched?

    1. Only one pair
    2. Only two pairs
    3. All three pairs
    4. None of the pairs
    Show answer

    Answer: B — Only two pairs

    Pairs 1 and 3 are correct. Pair 2 is wrong: the Rotterdam Convention sets the Prior Informed Consent procedure for hazardous chemicals and pesticides in trade, while persistent organic pollutants are the subject of the Stockholm Convention.
  15. Which one of the following is NOT one of the eight National Missions under India's National Action Plan on Climate Change (2008)?

    1. National Mission for a Green India
    2. National Water Mission
    3. National Mission for Sustainable Agriculture
    4. National Mission on Nuclear Energy
    Show answer

    Answer: D — National Mission on Nuclear Energy

    The eight missions are Solar, Enhanced Energy Efficiency, Sustainable Habitat, Water, Sustaining the Himalayan Ecosystem, Green India, Sustainable Agriculture and Strategic Knowledge for Climate Change. Nuclear energy is not among them, although it is a low-carbon source — which is exactly why it works as a distractor.
  16. India's Carbon Credit Trading Scheme, 2023, which establishes the Indian Carbon Market, was notified under:

    1. the Environment (Protection) Act, 1986
    2. the Energy Conservation Act, 2001, as amended in 2022
    3. the Air (Prevention and Control of Pollution) Act, 1981
    4. the Electricity Act, 2003
    Show answer

    Answer: B — the Energy Conservation Act, 2001, as amended in 2022

    The Energy Conservation (Amendment) Act, 2022 empowered the Centre to specify a carbon-credit trading scheme, and the 2023 scheme was notified under the Energy Conservation Act, with the Bureau of Energy Efficiency as administrator. The tempting Environment (Protection) Act is the parent of the separate Green Credit Programme, which is not a carbon market.